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Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics
- Source :
- Materials, Vol 6, Iss 4, Pp 1205-1236 (2013), Materials, Materials (Basel) 6 (2013): 1205–1236. doi:10.3390/ma6041205, info:cnr-pdr/source/autori:Carmela Martinelli, Gianluca M. Farinola, Vita Pinto, Antonio Cardone/titolo:Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics/doi:10.3390%2Fma6041205/rivista:Materials (Basel)/anno:2013/pagina_da:1205/pagina_a:1236/intervallo_pagine:1205–1236/volume:6
- Publication Year :
- 2013
- Publisher :
- MDPI AG, 2013.
-
Abstract
- In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices.
- Subjects :
- Materials science
conjugated materials
arylenevinylenes
chemistry.chemical_element
Review
lcsh:Technology
chemistry.chemical_compound
Stille cross-coupling
Photovoltaics
Organic chemistry
General Materials Science
organic semiconductors
lcsh:Microscopy
lcsh:QC120-168.85
chemistry.chemical_classification
lcsh:QH201-278.5
business.industry
lcsh:T
Aryl
Intermolecular force
Polymer
Stille reaction
Organic semiconductor
chemistry
lcsh:TA1-2040
fluorinated materials
Fluorine
lcsh:Descriptive and experimental mechanics
lcsh:Electrical engineering. Electronics. Nuclear engineering
Luminescence
business
lcsh:Engineering (General). Civil engineering (General)
lcsh:TK1-9971
Subjects
Details
- Language :
- English
- ISSN :
- 19961944
- Volume :
- 6
- Issue :
- 4
- Database :
- OpenAIRE
- Journal :
- Materials
- Accession number :
- edsair.doi.dedup.....6e42a5ca2332a5a11733f7d4ce1fe0fd