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Fluorination of some highly functionalized cycloalkanes: chemoselectivity and substrate dependence
- Source :
- Beilstein Journal of Organic Chemistry, r-CIPF: Repositorio Institucional Producción Científica del Centro de Investigación Principe Felipe (CIPF), Centro de Investigación Principe Felipe (CIPF), Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 2364-2371 (2017), r-CIPF. Repositorio Institucional Producción Científica del Centro de Investigación Principe Felipe (CIPF), instname
- Publication Year :
- 2017
-
Abstract
- A study exploring the chemical behavior of some dihydroxylated β-amino ester stereo- and regioisomers, derived from unsaturated cyclic β-amino acids is described. The nucleophilic fluorinations involving hydroxy–fluorine exchange of some highly functionalized alicyclic diol derivatives have been carried out in view of selective fluorination, investigating substrate dependence, neighboring group assistance and chemodifferentiation.
- Subjects :
- isomeria
Diol
chemistry.chemical_element
aminohapot
010402 general chemistry
01 natural sciences
Full Research Paper
lcsh:QD241-441
chemistry.chemical_compound
Alicyclic compound
Nucleophile
lcsh:Organic chemistry
fluorine
Structural isomer
Organic chemistry
stereoisomers
Chemoselectivity
lcsh:Science
ta116
chemistry.chemical_classification
amino acids
010405 organic chemistry
Organic Chemistry
Substrate (chemistry)
03.01. Általános orvostudomány
fluori
0104 chemical sciences
Chemistry
chemistry
chemoselectivity
Fluorine
Surface modification
functionalization
lcsh:Q
Subjects
Details
- ISSN :
- 18605397
- Volume :
- 13
- Database :
- OpenAIRE
- Journal :
- Beilstein journal of organic chemistry
- Accession number :
- edsair.doi.dedup.....6db278d83a773f962836b014f648556f