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MOF based on a longer linear ligand: electrochemical performance, reaction kinetics, and use as a novel anode material for sodium-ion batteries

Authors :
Yijing Wang
Xiaoya Chang
Weinqin Li
Huinan Guo
Mengying Wang
Shihui Yang
Yunwei Li
Yan Zhang
Lifang Jiao
Source :
Chemical Communications. 54:11793-11796
Publication Year :
2018
Publisher :
Royal Society of Chemistry (RSC), 2018.

Abstract

A metal-organic framework based on a longer linear ligand was rationally designed and evaluated as a novel anode material for sodium-ion batteries. It delivered a high specific capacity of 269 mA h g-1 with a desired voltage plateau and demonstrated excellent capacity retention (79.0% after 1000 cycles). In addition, its reaction kinetics was also investigated in detail by performing cyclic voltammetry and a predominantly diffusion-controlled process was clearly revealed.

Details

ISSN :
1364548X and 13597345
Volume :
54
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....6d8c7673fdfa87049266a126356ade63