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[RuIII(edta)(H2O)]−mediated oxidation of hydroxyurea with H2O2. Kinetic and mechanistic investigation

Authors :
Kalyan Asis Nayak
Erika Ember
Rudi van Eldik
Debabrata Chatterjee
Source :
Dalton Trans.. 39:1695-1698
Publication Year :
2010
Publisher :
Royal Society of Chemistry (RSC), 2010.

Abstract

Reported in this paper is the first example of a ruthenium complex, [Ru(III)(edta)(H(2)O)](-) (edta = ethylenediaminetetra-acetate), that catalyzes the oxidation of hydroxyurea in the presence of H(2)O(2), mimicking the action of peroxidase or catalase and shedding light on their possible mechanism of action.

Details

ISSN :
14779234 and 14779226
Volume :
39
Database :
OpenAIRE
Journal :
Dalton Trans.
Accession number :
edsair.doi.dedup.....6cc7604133b33204d46564e999d48a4b
Full Text :
https://doi.org/10.1039/b920839a