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[RuIII(edta)(H2O)]−mediated oxidation of hydroxyurea with H2O2. Kinetic and mechanistic investigation
- Source :
- Dalton Trans.. 39:1695-1698
- Publication Year :
- 2010
- Publisher :
- Royal Society of Chemistry (RSC), 2010.
-
Abstract
- Reported in this paper is the first example of a ruthenium complex, [Ru(III)(edta)(H(2)O)](-) (edta = ethylenediaminetetra-acetate), that catalyzes the oxidation of hydroxyurea in the presence of H(2)O(2), mimicking the action of peroxidase or catalase and shedding light on their possible mechanism of action.
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 39
- Database :
- OpenAIRE
- Journal :
- Dalton Trans.
- Accession number :
- edsair.doi.dedup.....6cc7604133b33204d46564e999d48a4b
- Full Text :
- https://doi.org/10.1039/b920839a