Rheological characterization of vinal gum, a galactomannan extracted from Prosopis ruscifolia seeds

Prosopis ruscifolia (or vinal tree) is an abundant plant from Argentina semiarid areas, whose seeds contain a galactomannan type interesting gum: vinal gum. The aim of this work was to analyze the rheological behavior of vinal gum suspensions and the consequences of its interactions with commercial gums widely employed in the food industry. Vinal gum aqueous suspensions were in good agreement with the Cox-Merz rule at concentrations lower or equal to 1% (w/w), which establishes an empirical relationship between complex and apparent viscosity. The flow curves of vinal gum could be defined only by two parameters -Newtonian viscosity (η0) and strain rate (γ˙0.1)- and the shear-thinning behavior of vinal gum complied with the generalized curve for other polysaccharides. In mixtures with xanthan gum, vinal gum exhibited a synergistic relationship on its elastic behavior (at a total gum concentration of 1% (w/w)). On the other hand, vinal gum showed no synergism with κ-carrageenan or sodium alginate at the same total concentration of polymer. Apparent viscosity of vinal gum aqueous suspensions showed Arrhenius type dependence with temperature, as other galactomannans. The rheological behavior was not dependent on shear time, and the thickening power of vinal gum was slightly affected by pH and ionic strength changes. The present work provides detailed information on rheological characteristics of a non-traditional galactomannan extracted from an abundant and available source, being a starting point for possible applications of vinal gum as thickening and/or stabilizing agent in food, pharmaceutical, paper, textile, oil and cosmetics industries. Fil: Busch, Verónica María. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina Fil: Delgado, Juan Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología; Argentina Fil: Santagapita, Patricio Roman. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina Fil: Wagner, Jorge Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología; Argentina Fil: Buera, Maria del Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina