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Zinc Promoted Addition of Methyl 2,2-Dihalocarboxylates to Carbonyl Compounds

Authors :
Luca Forti
Marta Benincasa
Ugo Maria Pagnoni
Emanuela Libertini
Franco Ghelfi
Source :
Synthetic Communications. 26:4113-4122
Publication Year :
1996
Publisher :
Informa UK Limited, 1996.

Abstract

Methyl 2,2-dihalocarboxylates add easily to carbonyl compounds in fair to good yields through the intermediate formation of 2-haloester enolates; the reaction is promoted by zinc, following a “Barbier” type procedure.

Subjects

Subjects :
carbonyl compounds
methyl-2-dihalocarboxylates
chemistry
Barbier reactions
Organic Chemistry
chemistry.chemical_element
Organic chemistry
Zinc

Details

ISSN :
15322432 and 00397911
Volume :
26
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi.dedup.....6b82059ede33c18be06be37525a52dce

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