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Fluoride, bifluoride and trifluoromethyl complexes of iridium(<scp>i</scp>) and rhodium(<scp>i</scp>)
- Source :
- Chemical Communications. 51:62-65
- Publication Year :
- 2015
- Publisher :
- Royal Society of Chemistry (RSC), 2015.
-
Abstract
- The ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support. Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed. Postprint
- Subjects :
- Trifluoromethyl
Chemistry
Inorganic chemistry
Metals and Alloys
chemistry.chemical_element
DAS
General Chemistry
Crystal structure
QD Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Rhodium
chemistry.chemical_compound
Bifluoride
Polymer chemistry
Materials Chemistry
Ceramics and Composites
QD
Reactivity (chemistry)
Iridium
Fluoride
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....6b6c77cd7046e42ce3738d2315e9529a