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Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis
- Source :
- Chemical Communications. 46:2501
- Publication Year :
- 2010
- Publisher :
- Royal Society of Chemistry (RSC), 2010.
-
Abstract
- The first asymmetric total synthesis of psychotrimine, a trimeric indole alkaloid, was accomplished via an asymmetric Ireland-Claisen rearrangement to construct a chiral quaternary carbon center, thereby establishing the absolute configuration of psychotrimine.
- Subjects :
- Indole alkaloid
Stereochemistry
Chemistry
Molecular Conformation
Metals and Alloys
Absolute configuration
Total synthesis
General Chemistry
Psychotrimine
Carbon
Catalysis
Indole Alkaloids
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Cell Line, Tumor
Materials Chemistry
Ceramics and Composites
Humans
Drug Screening Assays, Antitumor
Quaternary carbon
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....6b6c23c1efe278ee670497b9e17ff2c5