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Organic Solvent Free Process to Fabricate High Performance Silicon/Graphite Composite Anode

Authors :
Gao Liu
Chen Fang
Xiao Haiqing
Tianyue Zheng
Bai Hua
Source :
Journal of Composites Science, Volume 5, Issue 7, Journal of Composites Science, Vol 5, Iss 188, p 188 (2021)
Publication Year :
2021
Publisher :
Multidisciplinary Digital Publishing Institute, 2021.

Abstract

Cycling stability is a key challenge for application of silicon (Si)-based composite anodes as the severe volume fluctuation of Si readily leads to fast capacity fading. The binder is a crucial component of the composite electrodes. Although only occupying a small amount of the total composite mass, the binder has major impact on the long-term electrochemical performance of Si-based anodes. In recent years, water-based binders including styrene-butadiene rubber (SBR) and carboxymethyl cellulose (CMC) have attracted wide research interest as eco-friendly and low-cost alternatives for the conventional poly(vinylidene difluoride) (PVDF) binder in Si anodes. In this study, Si-based composite anodes are fabricated by simple solid mixing of the active materials with subsequent addition of SBR and CMC binders. This approach bypasses the use of toxic and expansive organic solvents. The factors of binder, silicon, and graphite materials have been systematically investigated. It is found that the retained capacities of the anodes are more than 440 mAh/g after 400 cycles. These results indicate that organic solvent free process is a facile strategy for producing high performance silicon/graphite composite anodes.

Details

Language :
English
ISSN :
2504477X
Database :
OpenAIRE
Journal :
Journal of Composites Science
Accession number :
edsair.doi.dedup.....68fad38e4b80c17ffee9f5b1c2d4e8ca
Full Text :
https://doi.org/10.3390/jcs5070188