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Can experiments select the configurational component of excess entropy?

Authors :
Lucia Comez
Silvia Corezzi
Daniele Fioretto
Publication Year :
2004

Abstract

We introduce an experimental method of assessing the vibrational and configurational components of the excess entropy of a liquid over crystal, based on a joined investigation of dynamic and thermodynamic properties as a function of temperature and pressure. We analyze light scattering, dielectric, calorimetric and dilatometric measurements of three prototype glass formers, orthoterphenyl, salol, and glycerol. In all cases we find that about 70% of the excess entropy is configurational in nature.<br />Comment: RevTeX4, 4 pages, 2 EPS figures

Details

Language :
English
Database :
OpenAIRE
Accession number :
edsair.doi.dedup.....68de0250fb624a4fd8751963eb728f57