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Electroconvection in a Homeotropic Bent-Rod Nematic Liquid Crystal Beyond the Dielectric Inversion Frequency
- Source :
- The Journal of Physical Chemistry B. 112:9753-9760
- Publication Year :
- 2008
- Publisher :
- American Chemical Society (ACS), 2008.
-
Abstract
- We characterize the structural transitions in an initially homeotropic bent-rod nematic liquid crystal excited by ac fields of frequency/well above the dielectric inversion point fi. From the measured principal dielectric constants and electrical conductivities of the compound, the Can-Helfrich conduction regime is anticipated to extend into the sub-megahertz region. Periodic patterned states occur through secondary bifurcations from the Freedericksz distorted state. An anchoring transition between the bend Freedericksz (BF) and degenerate planar (DP) states is detected. The BF state is metastable well above the Freedericksz threshold and gives way to the DP state, which persists in the field-off condition for several hours. Numerous +1 and -1 umbilics form at the onset of BF distortion, the former being largely of the chiral type. They survive in the DP configuration as linear defects, nonsingular in the core. In the BF regime, not far from fi, periodic Williams-like domains form around the umbilics; they drift along the director easy axis right from their onset. With increasing fi, the wave vector of the periodic domains switches from parallel to normal disposition with respect to the c vector. Well above fi, a broadband instability is found.
- Subjects :
- Condensed matter physics
business.industry
Chemistry
Bent molecular geometry
Homeotropic alignment
Degenerate energy levels
Dielectric
Instability
Surfaces, Coatings and Films
Condensed Matter::Soft Condensed Matter
Optics
Liquid crystal
Metastability
Excited state
Materials Chemistry
Physical and Theoretical Chemistry
business
Subjects
Details
- ISSN :
- 15205207 and 15206106
- Volume :
- 112
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry B
- Accession number :
- edsair.doi.dedup.....684c488ed7cebc4d00edbe41be3faec1