First quantitative measurements by IR spectroscopy of dioxins and furans by means of broadly tunable quantum cascade lasers

We demonstrate the possibility of a quantitative analysis of the concentration of several dioxins and furans, among the most toxic ones, by only using infrared absorption laser spectroscopy. Two broadly tunable quantum cascade lasers, emitting in the mid-infrared, have been used to measure the absorption spectra of dioxins and furans, dissolved in CCl4, in direct absorption mode. The minimum detectable concentrations are inferred by analyzing diluted samples. A comparison between this technique and standard Fourier transform spectroscopy has been carried out and an analysis of future perspectives is reported.