Mechanisms for removal of gaseous toluene in headspace using sonophysical and sonochemical effects at the gas–liquid interface

We developed a new method for removing gaseous substances by using high frequency (200 kHz) ultrasonic irradiation of water, and the effects of ultrasonic irradiation on gas-phase toluene were evaluated quantitatively for the first time. The removal ratio of gaseous toluene increased with increasing ultrasonic power, but the reaction was inhibited by the addition of radical scavengers, indicating that ultrasonic irradiation not only accelerated the dissolution of gaseous toluene but also induced toluene decomposition. The contribution made by OH radicals to the decomposition of gaseous toluene at the gas–liquid interface was confirmed by the difference in removal ratios between addition of KI and addition of tert-butyl alcohol. The toluene removal mechanism was investigated by studying the logarithmic plots for toluene concentration at specified times. The results of this study clearly showed the promotion of gaseous toluene dissolution and the reaction via OH radicals at the gas–liquid interface by sonophysical and sonochemical effects with both effects contributing to the removal of gaseous toluene. Furthermore, the total organic carbon concentration in the aqueous phase increased with increasing reaction time, indicating that the toluene degradation products were trapped and decomposed into low-molecular-weight organic compounds in the aqueous phase.