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Self-assembled monolayers of disulfide-functionalized diacetylenes on gold films and nanoparticles
- Source :
- Journal of physical chemistry. C 111 (2007): 345–353. doi:10.1021/jp0640777, info:cnr-pdr/source/autori:Alloisio M. (1), Demartini A. (1), Cuniberti C. (1), Petrillo G. (1), Thea S. (1), Giorgetti E. (2), Giusti A. (1), Dellepiane G. (1)/titolo:Self-assembled monolayers of disulfide-funzionalized diacetylenes on gold films and nanoparticles/doi:10.1021%2Fjp0640777/rivista:Journal of physical chemistry. C/anno:2007/pagina_da:345/pagina_a:353/intervallo_pagine:345–353/volume:111
- Publication Year :
- 2007
- Publisher :
- American Chemical Society, 2007.
-
Abstract
- This paper reports on the fabrication of self-assembled monolayers containing disulfide-functionalized diacetylenes. To this purpose, two diacetylene derivatives were synthesized: the novel 14-(9H-9-carbazolyl)tetradeca-10,12-diyn-1-yl disulfide (CDS9) and the henicosa-10,12-diyn-1-yl disulfide (DS9). Both monomers were employed to prepare two-dimensional self-assembled monolayers (2D-SAMs) by chemisorption on gold-sputtered platforms and three-dimensional self-assembled monolayers (3D-SAMs) on gold nanoclusters by direct synthesis in organic solvent. The chemisorbed diacetylenes were then converted to the polymeric form by exposure to UV radiation, and their morphological and spectroscopic properties investigated by several techniques. From SERS data it was inferred that both monomers show the same behavior, in that the highly conjugated blue phase was observed in the 3D-SAMs, while only the less extended red conformation was found in the corresponding 2D-SAMs.
- Subjects :
- Materials science
Diacetylene
Metal-organic nanohybrids
Nanoparticle
Self-assembled monolayer
Conjugated system
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Nanoclusters
chemistry.chemical_compound
General Energy
Monomer
chemistry
Chemisorption
Monolayer
Polymer chemistry
Organic chemistry
Polydiacetylenes
Physical and Theoretical Chemistry
Photoluminescence
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Journal of physical chemistry. C 111 (2007): 345–353. doi:10.1021/jp0640777, info:cnr-pdr/source/autori:Alloisio M. (1), Demartini A. (1), Cuniberti C. (1), Petrillo G. (1), Thea S. (1), Giorgetti E. (2), Giusti A. (1), Dellepiane G. (1)/titolo:Self-assembled monolayers of disulfide-funzionalized diacetylenes on gold films and nanoparticles/doi:10.1021%2Fjp0640777/rivista:Journal of physical chemistry. C/anno:2007/pagina_da:345/pagina_a:353/intervallo_pagine:345–353/volume:111
- Accession number :
- edsair.doi.dedup.....66cb1bf6464e97a1c3a3239405e5def0