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Gelatinized and nongelatinized starch/pp blends: effect of starch source and carboxylic and incorporation
- Source :
- Repositório Institucional da UFRGS, Universidade Federal do Rio Grande do Sul (UFRGS), instacron:UFRGS
- Publication Year :
- 2021
- Publisher :
- Springer Science and Business Media LLC, 2021.
-
Abstract
- Due to the environmental impact caused by incorrect disposal and the non-biodegradability of synthetic polymers, the packaging sector seeks renewable raw materials. An alternative is the utilization of natural renewable polymer, such as thermoplastic starch (TPS), mixed with synthetics. However, the chemical incompatibility between these two materials leads to the use of a compatibilizer agent. Even though the compatibilizer effect of carboxylic acid on TPS blends have been studied, the correlation between the carboxylic acid and the starch source has not been investigated yet. Thus, this study focuses on the effects of added carboxylic acids (myristic (C14) and stearic (C18) acid) and the starch sources (corn, cassava, and potato) on the properties and microstructure of blends with TPS/PP (70/30). The results suggested that the compatibilizer effect of acids depends on the starch source and the length of the acid chain, where cassava blends with C14 showed better results. Acid insertion increased tensile strength and deformation at break, but reduced the elastic modulus, indicating a plasticizer effect. This behavior was related to the formation of amylose and lipid complexes (endogenous or added) during heating. Torque reduction and Tg displacement were also observed for acid blends. The SEM images showed two different morphological dispersions and a non-gelatinization effect due to the acid insertion. Results suggested that acids act differently according to the starch source.
- Subjects :
- Materials science
Thermoplastic
Ácidos carboxílicos
Polymers and Plastics
Starch
Carboxylic acid
Starch source
Properties
02 engineering and technology
Raw material
Compatibility
010402 general chemistry
01 natural sciences
chemistry.chemical_compound
Amido termoplástico
Amylose
Ultimate tensile strength
Materials Chemistry
chemistry.chemical_classification
Organic Chemistry
Plasticizer
food and beverages
Polymer
021001 nanoscience & nanotechnology
0104 chemical sciences
Blends
chemistry
Chemical engineering
Propriedades dos materiais
0210 nano-technology
Subjects
Details
- ISSN :
- 15728935 and 10229760
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- Journal of Polymer Research
- Accession number :
- edsair.doi.dedup.....66b57cb24dca02f1186429f958a3a00a