Modelling of heat and mass transfer during the polymerisation of olefins on heterogeneous Ziegler catalysts

The modelling of heat and mass transfer during the gas and slurry phase polymerisation of olefins is examined. It is demonstrated that it might not be necessary in many cases to calculate concentration gradients in the growing catalyst/polymer complex, and that the currently used representation of heat transfer from small, highly active particles using standard chemical engineering correlations might not be accurate. Close examination of the morphology of catalyst particles shows that it is unlikely that the particles should be treated as a pseudo-homogeneous medium, and in fact the critical length scale for mass transfer is not the particle radius, but is much smaller. Furthermore, computational fluid dynamic simulations of single and interacting particles shows that convection is not the dominant heat transfer mechanism during the critical stages of the reaction.