Suppressing the Dynamic Oxygen Evolution of Sodium Layered Cathodes through Synergistic Surface Dielectric Polarization and Bulk Site-Selective Co-Doping

Utilizing anionic redox activity within layered oxide cathode materials represents a transformational avenue for enabling high-energy-density rechargeable batteries. However, the anionic oxygen redox reaction is often accompanied with irreversible dynamic oxygen evolution, leading to unfavorable structural distortion and thus severe voltage decay and rapid capacity fading. Herein, it is proposed and validated that the dynamic oxygen evolution can be effectively suppressed through the synergistic surface CaTiO