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Investigation of non-woven carbon paper as a current collector for sulfur positive electrode—Understanding of the mechanism and potential applications for Li/S batteries

Authors :
Fannie Alloin
Jean-Claude Leprêtre
S. Waluś
Jean-Frédéric Martin
Céline Barchasz
Renaud Bouchet
Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces (LEPMI )
Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut de Chimie du CNRS (INC)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])
Laboratoire d'Innovation pour les Technologies des Energies Nouvelles et les nanomatériaux (LITEN)
Institut National de L'Energie Solaire (INES)
Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)
Source :
Electrochimica Acta, Electrochimica Acta, Elsevier, 2016, 211, pp.697-703. ⟨10.1016/j.electacta.2016.05.204⟩, Electrochimica Acta, 2016, 211, pp.697-703. ⟨10.1016/j.electacta.2016.05.204⟩
Publication Year :
2016
Publisher :
HAL CCSD, 2016.

Abstract

International audience; Porous 3-D current collectors have been shown to be the primary choice in replacing classical 2D aluminum foil in applicable developments, especially those using carbon-based current collectors. In this study, we investigated the impact of using a non-woven carbon (NWC) based current collector for sulfur electrodes, in terms of performance and practical use in a commercial battery, keeping in mind the simplicity of electrode preparation method. The benefits of using NWC as a 3D current collector include high sulfur utilization for even highly loaded electrodes, lower polarization, and the provision of an efficient electrolyte reservoir. High discharge capacities up to ∼1200 mAh g−1 can be obtained at moderate C-rates, with relatively good capacity retention (

Details

Language :
English
ISSN :
00134686
Database :
OpenAIRE
Journal :
Electrochimica Acta, Electrochimica Acta, Elsevier, 2016, 211, pp.697-703. ⟨10.1016/j.electacta.2016.05.204⟩, Electrochimica Acta, 2016, 211, pp.697-703. ⟨10.1016/j.electacta.2016.05.204⟩
Accession number :
edsair.doi.dedup.....618052fe593a48dcb5b08f96a3af31c8
Full Text :
https://doi.org/10.1016/j.electacta.2016.05.204⟩