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Catalytic Hydrodeoxygenation of Fast Pyrolysis Bio-Oil from Saccharina japonica Alga for Bio-Oil Upgrading

Authors :
Hee Chul Woo
Hyun Tae Hwang
Jae Hyung Choi
Seung-Soo Kim
Hoang Vu Ly
Jinsoo Kim
Source :
Catalysts; Volume 9; Issue 12; Pages: 1043
Publication Year :
2019
Publisher :
Multidisciplinary Digital Publishing Institute, 2019.

Abstract

Biomass conversion via pyrolysis has been regarded as a promising solution for bio-oil production. Compared to fossil fuels, however, the pyrolysis bio-oils from biomass are corrosive and unstable due to relatively high oxygen content. Thus, an upgrading of bio-oil is required to reduce O component while improving stability in order to use it directly as fuel sources or in industrial processes for synthesizing chemicals. The catalytic hydrodeoxygenation (HDO) is considered as one of the promising methods for upgrading pyrolysis bio-oil. In this research, the HDO was studied for various catalysts (HZSM-5, metal, and metal-phosphide catalysts) to improve the quality of bio-oil produced by fast pyrolysis of Saccharina japonica (SJ) in a fluidized-bed reactor. The HDO processing was carried out in an autoclave at 350 °C and different initial pressures (3, 6, and 15 bar). During HDO, the oxygen species in the bio-oil was removed primarily via formation of CO2 and H2O. Among the gases produced through HDO, CO2 was observed to be most abundant. The C/O ratio of produced bio-oil increased when CoMoP/γ-Al2O3, Co/γ-Al2O3, Fe/γ-Al2O3, or HZSM-5 was used. The Co/γ-Al2O3 resulted in higher HDO performance than other catalysts. The bio-oil upgraded with Co/γ-Al2O3 showed high HHV (34.41 MJ/kg). With the use of catalysts, the kerosene-diesel fraction (carbon number C12–C14) was increased from 36.17 to 38.62–48.92 wt.%.

Details

Language :
English
ISSN :
20734344
Database :
OpenAIRE
Journal :
Catalysts; Volume 9; Issue 12; Pages: 1043
Accession number :
edsair.doi.dedup.....610ca507bd841c5023774a8b5da6e46d
Full Text :
https://doi.org/10.3390/catal9121043