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Superstructures of Organic-Polyoxometalate Co-crystals as Precursors for Hydrogen Evolution Electrocatalysts
- Source :
- Angewandte Chemie (International ed. in English). 61(3)
- Publication Year :
- 2021
-
Abstract
- Molybdenum-based carbides and nitrides have been considered as catalysts for the hydrogen evolution reaction (HER). One of the challenges in using Mo-based HER electrocatalysts is establishing well-defined precursors which can be transformed into Mo-based carbides/nitrides with controllable structure and porosity. We report the synthesis of a series of superstructures consisting of organic-polyoxometalate co-crystals (O-POCs) as a new type of metal-organic precursor to synthesize Mo-based carbides/nitrides in a controlled fashion and to use them for efficient catalytic hydrogen production. This protocol enables to create electrocatalysts composed of abundant nanocrystallites and heterojunctions with tunable micro- and nanostructure and mesoporosity. The best performing electrocatalyst shows high HER activity and stability with a low overpotential of 162 mV at 100 mA cm-2 (in comparison to Pt/C with 263 mV), which makes it one of the best non-noble metal HER catalysts in alkaline media and seawater.
Details
- ISSN :
- 15213773
- Volume :
- 61
- Issue :
- 3
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie (International ed. in English)
- Accession number :
- edsair.doi.dedup.....610471878a8dd2d1c5c1fefe2423d237