Back to Search
Start Over
Ion exchange and binding in selenium remediation materials using DNP-enhanced solid-state NMR spectroscopy
- Publication Year :
- 2019
- Publisher :
- Elsevier, 2019.
-
Abstract
- Selenate-loaded selenium water remediation materials based on polymer fibres have been investigated by dynamic nuclear polarization (DNP) enhanced solid-state NMR. For carbon-13 a significant reduction in experiment time is obtained with DNP even when compared with conventional carbon-13 NMR spectra recorded using larger samples. For the selenium remediation materials studied here this reduction allows efficient acquisition of {1H}-77Se heteronuclear correlation spectra which give information about the nature of the binding of the remediated selenate ions with the grafted side chains which provide the required ion exchange functionality.
- Subjects :
- Nuclear and High Energy Physics
Radiation
Ion exchange
010405 organic chemistry
Inorganic chemistry
Groundwater remediation
chemistry.chemical_element
General Chemistry
010402 general chemistry
01 natural sciences
Selenate
0104 chemical sciences
Ion
NMR spectra database
chemistry.chemical_compound
Solid-state nuclear magnetic resonance
Heteronuclear molecule
chemistry
Instrumentation
Selenium
Subjects
Details
- Language :
- English
- ISSN :
- 09262040
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....60a185cd705d395a0a73b73cb5899562