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Investigation into the vibrational yield of OH products in the OH+H+H channel arising from the dissociative recombination of H3O+

Authors :
Mathias Hamberg
Stefan Rosén
Jacek Semaniak
E. Vigren
Mats Larsson
Magdalena Kaminska
Magnus af Ugglas
Richard D. Thomas
Iryna Kashperka
Vitali Zhaunerchyk
Wolf D. Geppert
Source :
The Journal of Chemical Physics. 130:214302
Publication Year :
2009
Publisher :
AIP Publishing, 2009.

Abstract

The vibrational population of the hydroxyl radical, OH, formed in the OH+H+H channel arising from the dissociative recombination of the hydronium ion, H(3)O(+), has been investigated at the storage ring CRYRING using a position-sensitive imaging detector. Analysis shows that the OH fragments are predominantly produced in the v=0 and v=1 states with almost equal probabilities. This observation is in disagreement with earlier FALP experiments, which reported OH(v=0) as the dominant product. Possible explanations for this difference are discussed.

Details

ISSN :
10897690 and 00219606
Volume :
130
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi.dedup.....5e55663e63ad2ec43b6ae93ad5b81be9
Full Text :
https://doi.org/10.1063/1.3141434