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Synthesis of a Cyclic Co2Sn2 Cluster Using a Co– Synthon
- Source :
- Journal of the American Chemical Society, 140(41), 13195-13199. American Chemical Society, Journal of the American Chemical Society, Journal of the American Chemical Society, vol 140, iss 41
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- [Ar′SnCo]2 (1, Ar′ = C6H3-2,6{C6H3-2,6-iPr2}2), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)0.2][Co(1,5-cod)2] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)]2. This reaction illustrates a promising synthetic strategy to access uncommon metal clusters. The structure of 1 features a rhomboidal Co2Sn2 core with strong metal–metal bonds between tin and cobalt and a weaker tin–tin interaction. Reaction of 1 with white phosphorus afforded [Ar′2Sn2Co2P4] (2), the first molecular cluster compound containing phosphorus, cobalt and tin.
- Subjects :
- 010405 organic chemistry
White Phosphorus
Molecular cluster
ddc:540
Communication
Phosphorus
Synthon
chemistry.chemical_element
General Chemistry
010402 general chemistry
01 natural sciences
Biochemistry
Catalysis
0104 chemical sciences
3. Good health
Crystallography
Colloid and Surface Chemistry
chemistry
540 Chemie
Chemical Sciences
Cluster (physics)
Tin
Cobalt
Metal clusters
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 140
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....5de004adea70eee7af2126bfad8c5bec