Product Detection of the CH(X2Π) Radical Reaction with Cyclopentadiene: A Novel Route to Benzene

International audience; The reaction of the methylidyne radical (CH((XII)-I-2)) with cyclopentadiene (c-C5H6) is studied in the gas phase at 4 Ton and 373 K using a multiplexed photoionization mass spectrometer. Under multiple collision conditions, the dominant product channel observed is the formation of C6H6 + H. Fitting the photoionization spectrum using reference spectra allows for isomeric resolution of C6H6 isomers, where benzene is the largest contributor with a relative branching fraction of 90 (+/- 5)%. Several other C6H6 isomers are found to have smaller contributions, including fulvene with a branching fraction of 8 (+/- 5)%. Master Equation calculations for four different entrance channels on the C6H7 potential energy surface are performed to explore the competition between CH cycloaddition to a C=C bond vs CH insertion into C-H bonds of cyclopentadiene. Previous studies on CH addition to unsaturated hydrocarbons show little evidence for the C-H insertion pathway. The present computed branching fractions support benzene as the sole cyclic product from CH cycloaddition, whereas fulvene is the dominant product from two of the three pathways for CH insertion into the C-H bonds of cyclopentadiene. The combination of experiment with Master Equation calculations implies that insertion must account for similar to 10 (+/- 5)% of the overall CH + cyclopentadiene mechanism.