Back to Search
Start Over
Metallacyclopentadienes: synthesis, structure and reactivity
- Source :
- Chemical Society Reviews. 46:1160-1192
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- Metallacyclopentadienes, which possess two M–C(sp2) bonds and feature the structure of M(CR1CR2–CR3CR4), are an important class of five-membered metallacycles. They are considered as both reactive intermediates in the stoichiometric and catalytic transformations of organic molecules and useful precursors to main group element compounds, and have received considerable attention in organometallic chemistry, coordination chemistry and synthetic organic chemistry over the past six decades because of their unique metallacyclic structure. This review comprehensively presents the synthesis, structure and reactivity of the s-, p-, d- and f-block metallacyclopentadienes distributed in the whole periodic table. In addition, their application in synthetic organic chemistry and polymer chemistry is summarized. This review aims to be beneficial for the design and synthesis of novel metallacyclopentadienes, and for promoting the rapid development of metallacyclic chemistry.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Chemistry
Reactive intermediate
General Chemistry
010402 general chemistry
01 natural sciences
Combinatorial chemistry
0104 chemical sciences
Coordination complex
Catalysis
Organic molecules
chemistry.chemical_compound
Main group element
Organic chemistry
Organometallic chemistry
Subjects
Details
- ISSN :
- 14604744 and 03060012
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Chemical Society Reviews
- Accession number :
- edsair.doi.dedup.....5d6d7dee1d4433482ab4b7a615ac627a
- Full Text :
- https://doi.org/10.1039/c6cs00525j