Nickel(0) triethyl phosphite complex-catalyzed allylic substitution with retention of regio- and stereochemistry

Authors :: Akira Tsubouchi
Yasutaka Yatsumonji
Takeshi Takeda
Yusuke Ishida
Source :: Organic letters. 9(22)
Publication Year :: 2007
Abstract: Nickel(0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio- and stereochemistry.

Subjects :: Allylic rearrangement
Stereochemistry
organic chemicals
Organic Chemistry
food and beverages
chemistry.chemical_element
Biochemistry
law.invention
Catalysis
Nickel
chemistry.chemical_compound
chemistry
law
Organic chemistry
Phenols
Physical and Theoretical Chemistry
Walden inversion

Tools