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Bifunctional Pt/Au Janus electrocatalysts for simultaneous oxidation/reduction of furfural with bipolar electrochemistry

Authors :
Marisa Ketkaew
Sunpet Assavapanumat
Sorasak Klinyod
Alexander Kuhn
Chularat Wattanakit
Vidyasirimedhi Institute of Science and Technology [Thaïlande] (VISTEC)
Université de Bordeaux (UB)
Institut Polytechnique de Bordeaux (Bordeaux INP)
National Research Council of Thailand (NRCT5-RSA63025-03)
NSRF via the Program Management Unit for Human Resources & Institutional Development, Research and Innovation (B05F640207)
ERC Advanced grant ELECTRA no 741251
European Project: 741251,ERC Advanced ELECTRA
Source :
Chemical Communications, Chemical Communications, 2022, 58 (27), pp.4312-4315. ⟨10.1039/D1CC06759A⟩
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The sustainable conversion of biomass-derived compounds into high added-value products is a very important contemporary scientific challenge. In this context, we report here the simultaneous electro-oxidation/-reduction of a biomass-derived compound in a one-pot approach using bipolar electrochemistry. Bifunctional Pt/Au Janus electrocatalysts are employed for a selective conversion of furfural into both, furfuryl alcohol and furoic acid, which can't be achieved when using non-Janus particles. The results emphasize the benefits of bipolar electrochemistry in the frame of electrosynthesis processes.

Details

ISSN :
1364548X and 13597345
Volume :
58
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....5d163188ecdd30615bc9c2de4630127d