Copper-catalyzed 1,2-Borylacylation of 1,3-Enynes: synthesis of β-Alkynyl ketones

Authors :: Xin-Lian Liu
Lin Li
Han-Ze Lin
Jing-Tong Deng
Xiang-Zhi Zhang
Jin-Bao Peng
Source :: Chemical Communications. 58:5968-5971
Publication Year :: 2022
Publisher :: Royal Society of Chemistry (RSC), 2022.
Abstract: A copper catalyzed 1,2-borylacylation of 1,3-enynes with B2pin2 and acid chlorides has been developed. Highly functionalized α,α-disubstituted β-alkynyl ketones are readily prepared under mild conditions in moderate to good yields.

Subjects :: Chlorides
Alcohols
Materials Chemistry
Metals and Alloys
Ceramics and Composites
General Chemistry
Ketones
Copper
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials

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