Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis

Authors :: Alexander G. Medvedev
Dmitry A. Grishanov
Alexey A. Mikhaylov
Andrei V. Churakov
Tatiana A. Tripol’skaya
Roman V. Ottenbacher
Konstantin P. Bryliakov
Alexander I. Shames
Ovadia Lev
Petr V. Prikhodchenko
Source :: Inorganic Chemistry. 61:8193-8205
Publication Year :: 2022
Publisher :: American Chemical Society (ACS), 2022.
Abstract: The synthesis, transformation, and application in catalysis of triphenyllead hydroperoxide, the first dioxygen lead complex, are described. Triphenyllead hydroperoxide is characterized by

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