Widening the applicability of AnMBR for urban wastewater treatment through PDMS membranes for dissolved methane capture: Effect of temperature and hydrodynamics

[EN] AnMBR technology is a promising alternative to achieve future energy-efficiency and environmental-friendly urban wastewater (UWW) treatment. However, the large amount of dissolved methane lost in the effluent represents a potential high environmental impact that hinder the feasibility of this technology for full-scale applications. The use of degassing membranes (DM) to capture the dissolved methane from AnMBR effluents can be considered as an interesting alternative to solve this problem although further research is required to assess the suitability of this emerging technology. The aim of this study was to assess the effect of operating temperature and hydrodynamics on the capture of dissolved methane from AnMBR effluents by DMs. To this aim, a commercial polydimethylsiloxane (PDMS) DM was coupled to an industrial prototype AnMBR (demonstration scale) treating UWW at ambient temperature. Different operating temperatures have been evaluated: 11, 18, 24 and 30 degrees C. Moreover, the DM was operated at different ratios of liquid flow rate to membrane area (Q(L):A) ranging from 22 to 190 Lh(-1)m(-2) in order to study the resistance of the system to methane permeation. Methane recovery was maximized when temperature raised and Q(L):A was reduced, giving methane recovery efficiencies (MRE) of about 85% at a temperature of 30 degrees C and a Q(L):A of 25 Lh(-1)m(-2). The study showed that high Q(L):A ratios hinder methane recovery by the perturbation of the DM fibers, being this effect intensified at lower temperatures probably due the higher liquid viscosities. Also, the performed fouling evaluation showed that not significant membrane fouling may be expected in the DM unit at the short-term when treating AnMBR effluents. A resistance-in-series model was proposed to predict the overall mass transfer of the system according to operating temperature and Q(L):A, showing that methane capture was controlled by the liquid phase, which represented up to 80-90% of total mass transfer resistance. The energy and environmental evaluation performed in this study revealed that PDMS DMs would enhance energy recovery and environmental feasibility of AnMBR technology for UWW treatment, especially when operating at low temperatures. When MRE was maximized, the combination of AnMBR with DM achieved net energy productions and net greenhouse gas reductions of up to 0.87 kWh and 0.216 kg CO2-eq per m(3) of treated water.
This research work was supported by Generalitat Valenciana via Fellowships CPI-16-155 and C12747, as well as the financial aid received from the Ministerio de Economia y Competitividad via Juan de la Cierva Contract FJCI-2014-21616. This research work was also made possible thanks to co-financing by the European Financial Instrument for the Environment (LIFE+) during the implementation of the Project Membrane for ENERGY and WATER RECOVERYY "MEMORY" (LIFE13 ENV/ES/001353).