Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer

Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature loss of barrier properties. Therefore, delaminations limit the use of multilayer in these conditions. Delamination should result from interfacial shear stress, and plausibly from difference of shrinkage of the films, due to relaxation of internal stress. A method was developed for measuring the deformations of each individual film. The measurements indicate that the shrinkage is anisotropic and controls the decohesion in the multilayer. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016.