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V-optimal mixture designs for the qth degree model

Authors :
Utami Dyah Syafitri
Peter Goos
Source :
Chemometrics and intelligent laboratory systems
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

This paper revisits the problem of finding continuous V-optimal mixture designs for the qth degree model. For this problem, Liu and Neudecker [10] present general analytical expressions for the weights of the points of the simplex-centroid design and claim that the resulting designs are V-optimal. For a problem involving three mixture ingredients, Liu and Neudecker's results are in conflict with those of Laake [6]. We find that Laake's design for three ingredients is superior to that of Liu and Neudecker, and we establish the V-optimality of Laake's design and report V-optimal weights for the points of the simplex-centroid design for cases involvingmore than three ingredients. All newly proposed designs are superior to those of Liu and Neudecker.

Details

ISSN :
01697439
Volume :
136
Database :
OpenAIRE
Journal :
Chemometrics and Intelligent Laboratory Systems
Accession number :
edsair.doi.dedup.....5a1879c9dd21c86ef1b9728dcdcebfcd
Full Text :
https://doi.org/10.1016/j.chemolab.2014.04.019