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In situ synthesis of high dielectric constant GNPs/PBO nanocomposites with enhanced thermostability
- Source :
- IET Nanodielectrics (2019)
- Publication Year :
- 2019
- Publisher :
- Wiley, 2019.
-
Abstract
- Graphite nanoparticles (GNPs) were introduced into poly(p-phenylene benzobisoxazole) (PBO) matrix to produce composites via in situ polymerisation. Films of various composites were fabricated through the solution casting method in methanesulfonic acid (MSA) with the help of two sand core plates. The interlayer spacing of GNPs increased slightly confirmed by XRD as a result of an expanding effect caused by continuously formed PBO chains between the graphene nanosheets of GNPs during polymerisation. Also, due to the uniform dispersion of GNPs into PBO matrix, composite films exhibited an improved tensile strength (258 MPa, 72% higher than that of pure PBO) with 5 wt% loading of GNPs fillers. The initial decomposition temperature of the composite is ∼630°C. Besides, benefitting from the interfacial polarisation in this conductive filler/polymer system, the dielectric constant of the composites with 10 wt% loading of GNPs reached 6.96, which were over two times higher than that of pristine PBO polymer (2.91).
- Subjects :
- XRD
Composite number
Nanoparticle
high dielectric constant GNPs-PBO nanocomposites
thermal stability
law.invention
temperature 630.0 degC
law
Materials Chemistry
Graphite
dielectric polarisation
chemistry.chemical_classification
graphite
sand core plates
Polymer
Condensed Matter Physics
Atomic and Molecular Physics, and Optics
Electronic, Optical and Magnetic Materials
casting
interlayer spacing
thin films
graphite nanoparticles
graphene nanosheets
conductive filler-polymer system
scanning electron microscopy
Materials science
solution casting method
interfacial polarisation
PBO matrix
methanesulfonic acid
Dielectric
nanocomposites
MSA
lcsh:TA401-492
Thermal stability
Electrical and Electronic Engineering
polymers
GNPs fillers
pressure 258.0 MPa
Nanocomposite
Graphene
graphene
poly(p-phenylene benzobisoxazole) matrix
permittivity
thermostability
X-ray diffraction
chemistry
Chemical engineering
tensile strength
nanofabrication
nanoparticles
lcsh:Materials of engineering and construction. Mechanics of materials
pristine PBO polymer
polymerisation
filled polymers
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- IET Nanodielectrics (2019)
- Accession number :
- edsair.doi.dedup.....58ac2a8cec2d9ed2fd0f58d1e4748e33