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Controlled stoichiometric synthesis of DNA-quantum dot conjugates using Ni-mediated coordination chemistry
- Source :
- Chemical communications (Cambridge, England). 46(47)
- Publication Year :
- 2010
-
Abstract
- An oligonucleotide modified with Ni-nitrilotriacetate (NTA) was successfully synthesized and used for the stoichiometric functionalization of QDs. This synthetic approach allowed for the facile preparation of DNA–QD conjugates with a defined DNA/QD ratio using well-known Ni–histidine coordination chemistry. A FRET based DNA–QD nanoprobe was prepared using this method highlighting the great potential of this synthetic strategy.
- Subjects :
- chemistry.chemical_classification
Nitrilotriacetic Acid
DNA synthesis
Oligonucleotide
Metals and Alloys
Oligonucleotides
Nanoprobe
General Chemistry
Combinatorial chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Coordination complex
chemistry.chemical_compound
Förster resonance energy transfer
chemistry
Quantum dot
Nickel
Quantum Dots
Materials Chemistry
Ceramics and Composites
Fluorescence Resonance Energy Transfer
Surface modification
Histidine
DNA
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 46
- Issue :
- 47
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....57648ea0844cf158152e1316dfd7e0f8