Supramolecular structures from structurally persistent and surface active carbon dots in water

Carbon dots (CDs) have developed into an important class of nanomaterials that have attracted increasing attention during the past decades. Despite numerous types of CDs reported to date, research on their self-assembly is still limited. Herein, we report for the first time the self-assembly of CDs in water, which show concentration-dependent aggregation behavior. The CDs used have a structural motif of a fully carbonized core surrounded by a highly condensed, polymeric network, to which triethylene glycol monomethyl ether (TGME) chains are grafted. When dissolved in water, they show a low critical aggregation concentration (cac) of 0.07 mg mL