Back to Search Start Over

A transition metal–gallium cluster formed via insertion of 'GaI'

Authors :
Deborah L. Kays
Andrew James Valentine
William Lewis
Toby J. Blundell
Jonathan McMaster
Alexander J. Blake
Laurence J. Taylor
Source :
Chemical Communications. 56:8139-8142
Publication Year :
2020
Publisher :
Royal Society of Chemistry (RSC), 2020.

Abstract

The reaction between a two-coordinate Co(ii) diaryl complex and "GaI" affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster.

Subjects

Subjects :
Materials science
Metals and Alloys
chemistry.chemical_element
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Metal
Crystallography
chemistry
Transition metal
Group (periodic table)
visual_art
Materials Chemistry
Ceramics and Composites
visual_art.visual_art_medium
Cluster (physics)
Gallium

Details

ISSN :
1364548X and 13597345
Volume :
56
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....56a4847635fe2dbfb75633ec8285cfed
Full Text :
https://doi.org/10.1039/d0cc03559a
Full Text Access
View/download PDF

Tools

Authors Abstract Subjects Details