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A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide
- Source :
- The Analyst. 140:1119-1126
- Publication Year :
- 2015
- Publisher :
- Royal Society of Chemistry (RSC), 2015.
-
Abstract
- Molybdenum disulfide (MoS2) is an emerging material with some unique physical and electronic properties somewhat comparable to those of graphene. It was prepared with the use of a simple hydrothermal process, and has a layered structure similar to that of graphene. Also, it has a peroxidase-like catalytic activity and is able to catalyze the oxidation of the colorless peroxidase substrate, 3,3',5,5'-tetramethylbenzidine (TMB), in the presence of H2O2 to produce a blue product. This reaction used MoS2 as a useful peroxidase, which involved a colorimetric method for trace analysis of H2O2 in water, e.g. lake waters. This method is uncomplicated, inexpensive and highly sensitive for H2O2 in the 0.125-1.75 μM range (LOD: 0.08 μM). It is also quite stable in the presence of many common inorganic and organic potentially interfering compounds, e.g. metal ions as well as amino acids and sugars.
- Subjects :
- Trace Amounts
biology
Graphene
Metal ions in aqueous solution
Inorganic chemistry
Substrate (chemistry)
Biochemistry
Analytical Chemistry
Catalysis
law.invention
chemistry.chemical_compound
chemistry
law
Electrochemistry
biology.protein
Environmental Chemistry
Hydrogen peroxide
Molybdenum disulfide
Spectroscopy
Peroxidase
Subjects
Details
- ISSN :
- 13645528 and 00032654
- Volume :
- 140
- Database :
- OpenAIRE
- Journal :
- The Analyst
- Accession number :
- edsair.doi.dedup.....54b648960845719b0bf86deadbedc3bb