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A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide

Authors :
Yongnian Ni
Xinrong Guo
Fang-Ying Wu
Yong Wang
Serge Kokot
Source :
The Analyst. 140:1119-1126
Publication Year :
2015
Publisher :
Royal Society of Chemistry (RSC), 2015.

Abstract

Molybdenum disulfide (MoS2) is an emerging material with some unique physical and electronic properties somewhat comparable to those of graphene. It was prepared with the use of a simple hydrothermal process, and has a layered structure similar to that of graphene. Also, it has a peroxidase-like catalytic activity and is able to catalyze the oxidation of the colorless peroxidase substrate, 3,3',5,5'-tetramethylbenzidine (TMB), in the presence of H2O2 to produce a blue product. This reaction used MoS2 as a useful peroxidase, which involved a colorimetric method for trace analysis of H2O2 in water, e.g. lake waters. This method is uncomplicated, inexpensive and highly sensitive for H2O2 in the 0.125-1.75 μM range (LOD: 0.08 μM). It is also quite stable in the presence of many common inorganic and organic potentially interfering compounds, e.g. metal ions as well as amino acids and sugars.

Details

ISSN :
13645528 and 00032654
Volume :
140
Database :
OpenAIRE
Journal :
The Analyst
Accession number :
edsair.doi.dedup.....54b648960845719b0bf86deadbedc3bb