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Quinizarin Derivatives as Photoinitiators for Free-Radical and Cationic Photopolymerizations in the Visible Spectral Range
- Source :
- Macromolecules, Macromolecules, American Chemical Society, 2020, 53 (4), pp.1129-1141. ⟨10.1021/acs.macromol.9b02448⟩
- Publication Year :
- 2020
- Publisher :
- American Chemical Society (ACS), 2020.
-
Abstract
- We report the use of efficient visible-light sensitive allyl (QA) and epoxidized (QE) quinizarin derivatives as photoinitiating systems when combined with an appropriate electron donor (methyldiethanol amine, MDEA), an electron acceptor (iodonium salt, Iod), or a H donor (thiol derivative), for free-radical photopolymerization (FRP), cationic photopolymerization (CP), and a thiol–ene process. These systems have demonstrated excellent initiating properties under air or in laminated conditions under visible-light irradiation (LEDs@405, 455, and 470 nm or Xe lamp) for FRP, CP, or the thiol–ene process and appear more efficient than the well-known camphorquinone-based photoinitiating systems. As highlighted by electron paramagnetic resonance (EPR) and laser flash photolysis experiments, QA (or QE) acts either as an electron donor via a photoinduced electron transfer pathway with Iod or as a proton/proton-coupled electron transfer promoter with MDEA or a thiol derivative. Two types of interpenetrated polymer n...
- Subjects :
- Polymers and Plastics
Electron donor
02 engineering and technology
010402 general chemistry
Photochemistry
01 natural sciences
Photoinduced electron transfer
law.invention
Inorganic Chemistry
Electron transfer
chemistry.chemical_compound
law
Materials Chemistry
Electron paramagnetic resonance
ComputingMilieux_MISCELLANEOUS
chemistry.chemical_classification
Chemistry
Organic Chemistry
Cationic polymerization
Electron acceptor
021001 nanoscience & nanotechnology
0104 chemical sciences
[CHIM.POLY]Chemical Sciences/Polymers
Photopolymer
Flash photolysis
0210 nano-technology
Subjects
Details
- ISSN :
- 15205835 and 00249297
- Volume :
- 53
- Database :
- OpenAIRE
- Journal :
- Macromolecules
- Accession number :
- edsair.doi.dedup.....54807e74e403e390c005a6707e4e052b