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Modulation of liquid structure and controlling molecular diffusion using supramolecular constructs
- Source :
- Chemical Communications. 57:10604-10607
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- The non-equilibrium liquid structure was achieved by interfacial jamming of pillar[5]arene carboxylic acid (P[5]AA) mediated by hydrogen bonding interactions. The assembly was reversibly modulated via jamming to unjamming transition thus dynamically shaping the liquid droplets. Interestingly, these supramolecular constructs showed pH-switchable gated diffusion of encapsulants, hence showcasing a next generation smart release system.
- Subjects :
- chemistry.chemical_classification
Molecular diffusion
Materials science
Hydrogen bond
Diffusion
Carboxylic acid
Metals and Alloys
Pillar
Supramolecular chemistry
Jamming
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry
Chemical engineering
Modulation
Materials Chemistry
Ceramics and Composites
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....53217bcc240335eed4aadfda3a762026