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Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet
- Source :
- Chemical Communications. 57:5211-5214
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- A novel porous magnet consisting of cationic two-dimensional (2-D) layers extended by FeIII–CN–NiII linkages and pseudo-pillar dianions was synthesized. The size-selective guest adsorption behaviour of water and methanol molecules originates from the narrow bottle-neck-type pores in the flexible pseudo-pillared-layer structure, which results in the switching of the magnetic phases from antiferromagnetic to ferromagnetic, involving significant changes in the interlayer distance.
- Subjects :
- Materials science
Metals and Alloys
Cationic polymerization
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Crystallography
Adsorption
Ferromagnetism
Magnet
Materials Chemistry
Ceramics and Composites
Antiferromagnetism
Molecule
Porosity
Layer (electronics)
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....52641939a6992d866c5fec06058997d4