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Clay supported bimetallic Fe/Ni nanoparticles used for reductive degradation of amoxicillin in aqueous solution: Characterization and kinetics

Authors :
Xiulan Weng
Zuliang Chen
Ravendra Naidu
Zhengxian Chen
Mallavarapu Megharaj
Weng, Xiulan
Chen, Zhengxian
Chen, Zuliang
Mallavarapu, Megharaj
Naidu, Ravendra
Source :
Colloids and Surfaces A: Physicochemical and Engineering Aspects. 443:404-409
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

In this study, bentonite-supported Fe/Ni (B-Fe/Ni) nanoparticles were used to degrade amoxicillin (AMX) in aqueous solution due to their increased rate of degradation. More than 94% of AMX was removed using B-Fe/Ni, while only 84% was removed by Fe/Ni due to bentonite as the material to reduce the aggregation of Fe/Ni nanoparticles, which was confirmed by scanning electron microscopy (SEM) and X-ray energy-dispersive spectrometer (EDS). X-ray photoelectron spectroscopy (XPS) and FTIR spectral confirmed the presence of Fe (II) and Fe (III) in the B-Fe/Ni after reaction with AMX. Furthermore, the removal of AMX was consistent with pseudo first-order reaction kinetics. The reuse and stability of B-Fe/Ni in degradation of AMX show that it is a potential nanomaterial for the environmental remediation Refereed/Peer-reviewed

Details

ISSN :
09277757
Volume :
443
Database :
OpenAIRE
Journal :
Colloids and Surfaces A: Physicochemical and Engineering Aspects
Accession number :
edsair.doi.dedup.....50857339c0e20fa0a577009ba2eafb72