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Palladium-catalyzed intramolecular asymmetric hydroamination of alkynes
- Source :
- Scopus-Elsevier
- Publication Year :
- 2004
-
Abstract
- The Pd-catalyzed reaction of internal alkynes with tethered amino groups in the presence of PhCO2H and RENORPHOS as chiral phosphine ligand is reported. Various five- and six-membered nitrogen-containing heterocycles were obtained in good to high yield with moderate to high ee.
- Subjects :
- chemistry.chemical_classification
Intramolecular reaction
Stereochemistry
Chemistry
Ligand
Alkyne
chemistry.chemical_element
General Chemistry
General Medicine
Biochemistry
Medicinal chemistry
Catalysis
Pyrrole derivatives
chemistry.chemical_compound
Colloid and Surface Chemistry
Intramolecular force
Yield (chemistry)
Hydroamination
Phosphine
Palladium
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 126
- Issue :
- 6
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....50692505f2de3ce740853c4fc3cc95a6