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Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes
- Source :
- Arnold, P L, Turner, Z R, Germeroth, A I, Casely, I J, Nichol, G S, Bellabarba, R & Tooze, R P 2013, ' Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes ', Dalton Transactions, vol. 42, no. 5, pp. 1333-1337 . https://doi.org/10.1039/c2dt31698f
- Publication Year :
- 2012
-
Abstract
- The reactions of f-block silylamido N-heterocyclic carbene (NHC) complexes ([M(L)(N{SiMe3}2)2], M = Y, Ce, and U, L = bidentate alkoxy-tethered NHC ligand) with CO and CO2 have been studied and compared to each other, to those of selected [M(L)2 (N{SiMe3}2)] complexes, and to those of [M(N{SiMe3}2)3] to identify the effect of the labile NHC group on the small molecule activation chemistry. The small molecules COS and N2CPh2 have also been studied.
Details
- ISSN :
- 14779234
- Volume :
- 42
- Issue :
- 5
- Database :
- OpenAIRE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Accession number :
- edsair.doi.dedup.....506462c7851426c1416e3c8c5a1b2adc