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A twofold parallel interpenetration network from the assembly of a flexible spacer and CuI: poly[μ-iodido-μ-4,4′-(methylenedithio)dipyridine-κ2N:N′-copper(I)]
- Source :
- Acta Crystallographica Section C Crystal Structure Communications. 64:m76-m78
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography (IUCr), 2008.
-
Abstract
- The title compound, [CuI(C(11)H(10)N(2)S(2))](n), is built around centrosymmetric dinuclear Cu(2)I(2) cores, each of which is linked to four neighboring Cu(2)I(2) units via flexible dithioether ligands, viz. 4,4'-(methylenedithio)dipyridine, to form a two-dimensional grid containing rhombus-shaped cavities with diagonal distances of ca 15 and 22 A. Two of these networks interpenetrate in a woven fashion, and the resulting structure does not possess any open channels or cavities. Each Cu atom is in a distorted tetrahedral coordination environment.
Details
- ISSN :
- 01082701
- Volume :
- 64
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section C Crystal Structure Communications
- Accession number :
- edsair.doi.dedup.....4f97954a131083db020d216aef405701