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Waste PET upcycling to conductive carbon-based composite through laser-assisted carbonization of UiO-66

Authors :
Dmitry Kogolev
Oleg Semyonov
Nadezhda Metalnikova
Maxim Fatkullin
Raul D. Rodriguez
Petr Slepicka
Yusuke Yamauchi
Olga Guselnikova
Rabah Boukherroub
Pavel S. Postnikov
Tomsk Polytechnic University [Russie] (UPT)
University of Queensland [Brisbane]
University of Chemistry and Technology Prague (UCT Prague)
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 (IEMN)
Centrale Lille-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF)-JUNIA (JUNIA)
Université catholique de Lille (UCL)-Université catholique de Lille (UCL)
NanoBioInterfaces - IEMN (NBI - IEMN)
Université catholique de Lille (UCL)-Université catholique de Lille (UCL)-Centrale Lille-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF)-JUNIA (JUNIA)
The authors thank the central laboratories of TPU (Analytical center) for the XPS measurements and Tomsk Regional Core Shared Research Facilities Center of National Research Tomsk State University for the SEM, ICP-MS and CHNS measurements. The research has been supported by the Russian-French project No. 075-15-2022-244 in the frame of PHC 'Kholmogorov'. R. B. acknowledges financial support from the CPER 'Wavetech'. This work was performed in part at the Queensland node of the Australian National Fabrication Facility, a company established under the National Collaborative Research Infrastructure Strategy to provide nano and microfabrication facilities for Australia’s researchers.
Source :
Journal of Materials Chemistry A, Journal of Materials Chemistry A, 2023, 11 (3), pp.1108-1115. ⟨10.1039/d2ta08127j⟩
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

International audience; The upcycling of waste polymers into novel materials with high added value is a vital task for modern chemical engineering. Here, we propose diversifying waste polyethylene terephthalate (PET) upcycling to materials with enhanced photothermal properties by laser-assisted carbonization of surface-grown UiO-66. The UiO-66 homogenous layer was formed using a solvo-thermal procedure on the surface of recycled PET sheets. The treatment by a 405 nm laser system allowed the formation of a carbonaceous layer with enhanced electrical conductivity and photothermal properties due to the presence of zirconium carbide and graphene. The developed approach opens new perspectives in the application of upcycled PET-based materials.

Details

ISSN :
20507496 and 20507488
Volume :
11
Database :
OpenAIRE
Journal :
Journal of Materials Chemistry A
Accession number :
edsair.doi.dedup.....4f46e64e6231ed9811044683413a4fa2