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Functionalization of P4 through Direct P-C Bond Formation
- Source :
- Borger, J E, Ehlers, A W, Slootweg, J C & Lammertsma, K 2017, ' Functionalization of P 4 through Direct P−C Bond Formation ', Chemistry-A European Journal, vol. 23, no. 49, pp. 11738-11746 . https://doi.org/10.1002/chem.201702067, Chemistry-A European Journal, 23(49), 11738-11746. Wiley-VCH Verlag, Chemistry (Weinheim an Der Bergstrasse, Germany)
- Publication Year :
- 2017
-
Abstract
- Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P−C bond formations have only recently emerged. These include the use of metal organyls, carbenes, carboradicals, and photochemical approaches. The versatile product scope enables the preparation of both industrially relevant organophosphorus compounds, as well as a broad range of intriguing new compound classes. Herein we provide a concise overview of recent breakthroughs and outline the acquired fundamental insights to aid future developments.
- Subjects :
- Nucleophilic addition
phosphorus anions
010405 organic chemistry
Chemistry
Organic Chemistry
Minireviews
Nanotechnology
organophosphorus compounds
General Chemistry
main group chemistry
Bond formation
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
nucleophilic addition
Organic chemistry
Surface modification
Minireview
phosphorus
SDG 6 - Clean Water and Sanitation
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 49
- Database :
- OpenAIRE
- Journal :
- Chemistry-A European Journal
- Accession number :
- edsair.doi.dedup.....4d362e4dc2ed9f55d21a2b811ef5b5c7