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Modelling of the Erosive Dissolution of Metal Oxides in a Deep Eutectic Solvent—Choline Chloride/Sulfosalicylic Acid—Assisted by Ultrasonic Cavitation

Authors :
Oleg M. Gradov
Inna V. Zinov’eva
Yulia A. Zakhodyaeva
Andrey A. Voshkin
Source :
Metals; Volume 11; Issue 12; Pages: 1964, Metals, Vol 11, Iss 1964, p 1964 (2021)
Publication Year :
2021
Publisher :
Multidisciplinary Digital Publishing Institute, 2021.

Abstract

Here we report on the results concerning the influence of ultrasound on the dissolution process of metal oxides CoO, Ni2O3 and Mn2O3 in choline chloride/sulfosalicylic acid as a deep eutectic solvent. The mechanism of dissolution under cavitation conditions with ultrasonic assistance is described. Theoretical research resulted in equations describing the dissolution process kinetics and linking its basic parameters. Optimal conditions for the most effective ultrasound application were found. Experimental data on dissolution kinetics of metal oxides in deep eutectic solvents was also obtained. It was discovered that experimental data correlates well with theoretical calculations, which confirms the correctness of developing a picture about the physicochemical nature of the process under study.

Details

Language :
English
ISSN :
20754701
Database :
OpenAIRE
Journal :
Metals; Volume 11; Issue 12; Pages: 1964
Accession number :
edsair.doi.dedup.....4ccfe8664c33f397640fdec24c5deb7a
Full Text :
https://doi.org/10.3390/met11121964