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CO2 Mineralization Using Brine Discharged from a Seawater Desalination Plant
- Source :
- Minerals; Volume 7; Issue 11; Pages: 207, Minerals, Vol 7, Iss 11, p 207 (2017)
- Publication Year :
- 2017
- Publisher :
- Multidisciplinary Digital Publishing Institute, 2017.
-
Abstract
- CO2 mineralization is a method of sequestering CO2 in the form of carbonated minerals. Brine discharged from seawater desalination is a potential source of Mg and Ca, which can precipitate CO2 as forms of their carbonate minerals. The concentration of Mg and Ca in brine are twice those in the seawater influent to desalination process. This study used a cycle for CO2 mineralization that involves an increase in the pH of the brine, followed by CO2 bubbling, and, finally, filtration. To the best of our knowledge, this is the first time that non-synthesized brine from a seawater desalination plant has been used for CO2 mineralization. The resulting precipitates were CaCO3 (calcite), Mg5(CO3)4(OH)2·4H2O (hydromagnesite), and NaCl (halite) with these materials being identified by X-ray Diffraction (XRD), Fourier transform infrared (FTIR) and thermo gravimetric-differentail thermal Analysis (TGA)-DTA. Despite the presence of Ca with Mg in brine being unfavorable for the precipitation of Mg carbonate, Mg reacted with CO2 to form hydromagnesite at a yield of 86%. Most of the Ca formed calcite, at 99% yield. This study empirically demonstrates that brine from seawater desalination plants can be used for CO2 mineralization.
- Subjects :
- lcsh:QE351-399.2
Carbonate minerals
Mineralogy
carbonates
02 engineering and technology
engineering.material
Desalination
desalination
chemistry.chemical_compound
020401 chemical engineering
CO2 mineralization
0204 chemical engineering
Hydromagnesite
seawater
Calcite
lcsh:Mineralogy
brine
Geology
021001 nanoscience & nanotechnology
Geotechnical Engineering and Engineering Geology
Brine
chemistry
Environmental chemistry
engineering
Carbonate
Halite
Seawater
0210 nano-technology
Subjects
Details
- Language :
- English
- ISSN :
- 2075163X
- Database :
- OpenAIRE
- Journal :
- Minerals; Volume 7; Issue 11; Pages: 207
- Accession number :
- edsair.doi.dedup.....4c03b86fa82092830644b3456610e300
- Full Text :
- https://doi.org/10.3390/min7110207