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Effects of open inelastic channels in the resonant dissociative recombination of HeH+

Authors :
Kulander Kc
Rescigno Tn
Ann E. Orel
Source :
Physical review letters. 74(24)
Publication Year :
1995

Abstract

We show that {ital ab} {ital initio} theory provides a quantitative description of resonant dissociative recombination. Using a variational method for the electronic scattering problem and a wave packet treatment of the dissociation dynamics, we obtain excellent agreement with recent absolute cross sections for dissociative recombination of {sup 3}HeH{sup +} in the 10--30 eV region. The cross section contains significant contributions from several resonance states, some of which autoionize into electronically excited states. A proper multichannel treatment of the resonances is needed to achieve quantitative agreement with experiment.

Details

ISSN :
10797114
Volume :
74
Issue :
24
Database :
OpenAIRE
Journal :
Physical review letters
Accession number :
edsair.doi.dedup.....4bbd27136deacfb0dc00c0fe06aa33cc