Grain size partitioning of platinum-group elements in road-deposited sediments: Implications for anthropogenic flux estimates from autocatalysts

Twelve road-deposited sediment samples were analyzed for platinum-group elements (PGEs) and Pb in the63 microm fraction of an urban watershed in Hawaii. Three samples were further fractionated into five size classes, from 63-125 microm to 1000-2000 microm, and these were analyzed for PGEs and Pb. Concentrations in the63 microm fraction reached 174 microg/kg (Pt), 101 microg/kg (Pd), 16 microg/kg (Rh), and 1.3 microg/kg (Ir). Enrichment ratios followed the sequence RhPt=PdIr. Iridium was geogenic in origin, while the remaining PGEs indicated significant anthropogenic contamination. Palladium, Pt and Rh concentrations and enrichment signals were consistent with PGE bivariate ratios and PGE partitioning in three-way catalysts. Size partitioning indicated that the63 microm fraction had the lowest PGE concentrations and mass loading percentages. These data suggest that autocatalyst PGE flux estimates into the environment will be significantly underestimated if only a fine grain size fraction is analyzed.